IUPAC nomenclature of Carboxylic acids

Compound (common name, Structural

formula, IUPAC Name)

IUPAC Name

Prefix with position number

Root used

Primary suffix

Secondary Suffix

Formic acid HCOOH

methanoicacid – meth ane/ oicacid

Acetic acid

CH3COOH

Ethanoic acid

– eth ane/ oicacid

Isobutyric acid

(CH3)2CHCOOH

2 – methylpropanoic acid

2 – methyl prop ane/ oicacid

Phenyl acetic acid

CH2COOH

2-phenyl ethanoic acid

2-phenyl eth ane/ oicacid

Oxalic acid HOOC - COOH

ethane–1, 2 – dioicacid

– eth ane 1, 2 –

dioicacid

XII U12-Carbonyl Compounds.indd 168 2/19/2020 5:15:13 PM

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C ompound(common name, Structural formula, IUPAC Name) IUPAC Name
Prex with position number Rootused Primar y sux Secondar ySux
Formic acidHCO OHmethanoicacid meth ane/ oicacid
Acetic acidCH CO OHEthanoic acid3 eth ane/ oicacid
Isobutyric acid(CH ) CHCO OH2 – methylpropanoic acid3 2 2 – methyl prop ane/ oicacid
Phenyl acetic acidCH COOH2-phenyl ethanoic acid2 2-phenyl eth ane/ oicacid
Oxalic acidHOOC - COOHethane–1, 2 – dioicacid eth ane 1, 2 – dioicacid

169

Malonic acid

HOOC-CH2-COOH

Propanedioic acid

– prop ane 1, 3 –

dioicacid

Succinic acid HOOC-(CH2)2-COOH

Butanedioic acid – but ane

1, 4 – dioicacid

Glutaric acid HOOC-(CH2)3-COOH

Pentanedioic acid – pent ane

1,5 – dioicacid

Adipic acid HOOC-(CH2)4-COOH

Hexanedioic acid – hex ane

1,6 – dioicacid


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